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Information Journal Paper

Title

Improvement of Nanosized CuO-Fe2O3/cordierite System by Li2O-treatment for wastewater treatment; carcinogenic dyes removal, phenol degradation and hydrogen peroxide decomposition

Pages

  175-187

Abstract

 A mixture of 10 wt% CuO-10 wt% Fe2O3 supported on Cordierite were prepared by wet impregnation. The as-prepared solids doped with Li2O (0. 75-3 mol %) were calcined at 500-900 º C. The crystalline phase, morphology, and surface area were investigated by XRD, HR-TEM and N2-adsoprtion-desorption. Moreover, their photocatalytic activities of samples calcined at 700° C on the degradation of phenol were evaluated under UV-irradiation. The catalytic activity of different solids toward H2O2 decomposition was studied. Nano-materials were used to adsorb dyes as Remazole-Red and Congo-Red from aqueous solution. The sorption process was in good agreement of pseudo-second order equation and the Langmuir equation through their adsorption kinetics and isotherms, respectively. The CuO-Fe2O3/ Cordierite doped with 0. 75% Li2O at 700 º C adsorbent was found to possess the highest removal efficiency of Remazole-Red and/or Congo-Red dyes and potentially lowering capital and operational costs for \practical applications. The highest removal efficiency of the anionic dyes over 0. 75% Li2O at 700 º C can be discussed by observing the appearance of new active phases as CuO, CuFe2O4 and LiCuO, decreasing the crystallite size of these active phases. 0. 75 mol% Li2O has the greatest activity in H2O2 decomposition reached 700 %. This result may be related to the lowest particle size and the highest surface area of this sample, which also produced a large number of electrons donating active sites for H2O2 decomposition.

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    APA: Copy

    Al Harby, Noof F., Badawy, Abdelrahman A., & Ibrahim, Shaimaa M.. (2019). Improvement of Nanosized CuO-Fe2O3/cordierite System by Li2O-treatment for wastewater treatment; carcinogenic dyes removal, phenol degradation and hydrogen peroxide decomposition. JOURNAL OF ULTRAFINE GRAINED AND NANOSTRUCTURED MATERIALS, 52(2), 175-187. SID. https://sid.ir/paper/347430/en

    Vancouver: Copy

    Al Harby Noof F., Badawy Abdelrahman A., Ibrahim Shaimaa M.. Improvement of Nanosized CuO-Fe2O3/cordierite System by Li2O-treatment for wastewater treatment; carcinogenic dyes removal, phenol degradation and hydrogen peroxide decomposition. JOURNAL OF ULTRAFINE GRAINED AND NANOSTRUCTURED MATERIALS[Internet]. 2019;52(2):175-187. Available from: https://sid.ir/paper/347430/en

    IEEE: Copy

    Noof F. Al Harby, Abdelrahman A. Badawy, and Shaimaa M. Ibrahim, “Improvement of Nanosized CuO-Fe2O3/cordierite System by Li2O-treatment for wastewater treatment; carcinogenic dyes removal, phenol degradation and hydrogen peroxide decomposition,” JOURNAL OF ULTRAFINE GRAINED AND NANOSTRUCTURED MATERIALS, vol. 52, no. 2, pp. 175–187, 2019, [Online]. Available: https://sid.ir/paper/347430/en

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