Hammett CONSTANTs (s) can be important factor to understanding substitution and position effects on benzoic acid. This report describes a computational study of DGo and s for six substituted benzoic acid (X=F, Cl, OH, NH2, CN, NO2) and phenylacetic acid substituted (X=OH, NH2) at para and meta positions ingas and aqueousphases by DFT method and comparesit to available experimental and theoretical results.