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Title

UNSYMMETRICAL BINUCLEAR CYCLOPLATINATED (II) COMPLEXES, SYNTHESIS, CHARACTERIZATION, SPECTROSCOPIC AND COMPUTATIONAL STUDIES

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Abstract

 BACKGROUND: SYNTHESIS AND INVESTIGATION OF BINUCLEAR COMPLEXES, AS THE SIMPLEST MULTIMETALLIC SYSTEMS, HAVE BEEN PARTICULARLY IMPORTANT DUE TO THEIR APPLICATIONS IN MANY FIELDS SUCH AS CATALYSIS. IN THIS AREA, THE CONNECTION OF CYCLOMETALATED ORGANOPLATINUM COMPOUNDS TO EACH OTHER BY USING APPROPRIATE BRIDGING LIGAND SUCH AS BIPHOSPHINE LIGANDS (E.G., DPPM=BIS (DIPHENYLPHOSPHINO) METHANE) WOULD HAVE GREAT IMPACTS ON THEIR REACTIVITY AND PROPERTIES DUE TO PRESENCE OF NEW SET OF ELECTRONIC AND STERIC EFFECTS [1-3]...

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