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Title

THEORETICAL INVESTIGATION INTO THE GOLD-CATALYZED REACTIVITY OF CYCLOPROPENYLMETHYL ACETATES

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Abstract

 BACKGROUND: CYCLOPROPENYLMETHYL ACETATES HAVE BEEN SHOWN TO UNDERGO RAPID AND STEREOSELECTIVE GOLD CATALYZED REARRANGEMENT TO Z-ACETOXYDIENES IN HIGH YIELD. DFT CALCULATIONS HAVE SHOWN THAT WHILE SEVERAL REACTION PATHWAYS CAN BE ENVISAGED ONLY ASINGLE, RING-OPENING ONE OPERATES...

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