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Title

POTENTIOMETRIC INVESTIGATION OF COMPLEXATION BETWEEN PD2+ION AND ACRIDINEDIPICOLINICACID PROTON-TRANSFER SYSTEM IN DIOXANE/H2O SOLVENT AND COMPARISON WITH SOLID STATE RESULTS

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Abstract

 THE PROTONATION CONSTANTS OF DIPICOLINIC ACID (DIPIC) AND ACRIDINE (ACR), THE EQUILIBRIUM CONSTANTS FOR THE DIPIC-ACR PROTON TRANSFER SYSTEM AND THE STOICHIOMETRY AND STABILITY OF COMPLEXATION OF THIS SYSTEM WITH PD2+ION IN 50% DIOXANE-50% WATER (V/V) SOLVENT WERE INVESTIGATED BY POTENTIOMETRIC PH TITRATION METHOD. THE STOICHIOMETRY OF THE MOST COMPLEXES SPECIES IN SOLUTION WERE COMPARED WITH CORRESPONDING CRYSTALLINE METAL ION COMPLEXES.

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