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Title

EFFECT GUEST MOLECULES ON THE STRUCTURAL AND ELECTRONIC PROPERTIES OF THE ZEOLITE LI-ABW

Writers

 CLARKE S.

Pages

 Start Page | End Page

Abstract

 INTRODUCTION: THE CONFINEMENT OF MOLECULES IN ORDERED MATRICES IS A TECHNOLOGICALLY RELEVANT APPROACH FOR THE TAILORING OF CHEMICAL AND PHYSICAL PROPERTIES OF NEW KINDS OF MATERIALS. ZEOLITES, WITH THEIR NANOSIZED ARRAYS OF CAGES AND CHANNELS ARE IDEAL MATRICES WHERE SUCH CONFINEMENT MAY BE SUCCESSFULLY ACHIEVED. HOWEVER, MUCH EFFORT IS NECESSARY IN ORDER TO UNDERSTAND, AT A MICROSCOPIC LEVEL, THE MAIN CHARACTERISTICS OF THE CONFINED-SPECIES-MATRIX INTERACTIONS RESPONSIBLE FOR THE STABILITY AND THE BEHAVIOR OF SUCH NANO-COMPOSITE MATERIALS. DUE TO THE VERY NATURE OF THE SYSTEMS, I.E. MOLECULES, IONS AND/OR OLIGOMERS ENCAPSULATED IN CAGES AND CHANNELS, WHOSE SECTIONS ARE COMPARABLE TO (AT LEAST) ONE SIZE OF THE GUEST COMPOUNDS, A DETAILED KNOWLEDGE OF THE ENERGETICS, STATISTICAL MECHANICS AND IN GENERAL OF THE HOST-GUEST INTERACTIONS MAY BE OF PARAMOUNT INTEREST FOR SYNTHESIS AND MATERIALS SCIENCE RESEARCH [1, 2].

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