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Information Journal Paper

Title

New Homogeneous And Robust Catalyst for Heck and Suzuki Reactions

Writers

Sayahi M.H. | Mirza B.

Pages

 Start Page 327 | End Page 332

Keywords

N 
(pyridin 
2 
ylmethyl) benzamide;Homogeneous Pd catalyst 

Abstract

 A novel and efficient palladium-based homogeneous catalyst was fabricated and used as a robust catalyst in Suzuki– Miyaura cross-coupling and Heck reactions. 2-amino-N-(pyridin-2-ylmethyl)benzamide was introduced as a versatile ligand for palladiumcatalyzed cross-coupling reactions. The desired active and stable homogeneous Pd catalyst was prepared via the coordination of Pd with 2-amino-N-(pyridin-2-ylmethyl)benzamide and fully characterized. The catalyst exhibited excellent activity in Suzuki– Miyaura cross-coupling and Heck reactions. The proposed protocol featured mild reaction conditions and efficiency using LiOH as base.

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