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Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) | Year:0 | Volume:7 | Issue:4 | Start Page:807 | End Page:813

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Information Journal Paper

Title

SYNTHESIS AND SPECTROSCOPY STUDIES OF NEW NEODYMIUM(III) COMPLEXES WITH CYANAMIDE DERIVATIVES AS N-DONOR LIGAND

Pages

 Start Page 807 | End Page 813

Keywords

Abstract

 Four new complexes [Nd (phen)2 (pcyd)3] (1), [Nd (phen) 2 (2-Clpcyd) 3] (2), [Nd (phen) 2 (2, 3, 5-Cl3pcyd) 3] (3) and [Nd (phen) 2 (2, 3, 4, 5-Cl4pcyd) 3] (4) where pcyd=phenylcyanamide anion, 2-Clpcyd= (2-chlorophenyl) cyanamide anion, 2, 3, 5- Cl3pcyd= (2, 3, 5-threechlorophenyl) cyanamide anion and 2, 3, 4, 5-Cl4pcyd= (2, 3, 4, 5-tetrachlorophenyl) cyan amide anion, were prepared and characterized by IR, UV-Vis and 1H NMR spectroscopy as well as elemental analysis. The 1H NMR spectra of these complexes show broadening of ligand protons attributed to coordination of paramagnetic center.

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