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Title

SYNTHESIS AND CRYSTAL STRUCTURE OF AN UNUSUAL MIXED CRYSTAL CONTAINING AN OXORHENIUM(V) AND IMIDORHENIUM(V) COMPLEX

Pages

 Start Page 775 | End Page 780

Keywords

OXORHENIUM(V) 

Abstract

 An unusual MIXED CRYSTAL of a SQUARE-PYRAMIDAL oxorhenium(V), [ReOCl(Hdua)], and an octahedral IMIDOrhenium(V) complex, [Re(dua)Cl2(PPh3)], was prepared from the reaction of trans-[ReOCl3(PPh3)2] and (6Z)-6-(2-aminobenzylideneamino)- 5-amino-1,3-dimethylpyrimidine-2,4(1H,3H)-dione (H3dua) in ethanol. Characterization was performed by single crystal X-ray structure determination and IR spectroscopy. The chelate Hdua is coordinated as a tridentate diamido-imine, and dua is chelated as an IMIDO-imino-amide.

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