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Title

SELECTIVE, METAL-FREE OXIDATION OF SULFIDES TO SULFOXIDES USING 30% HYDROGEN PEROXIDE CATALYZED WITH N-BROMOSUCCINIMIDE (NBS) UNDER NEUTRAL BUFFERED REACTION CONDITIONS

Writers

KARIMI B. | ZAREEI D.

Pages

 Start Page 103 | End Page 107

Abstract

 Various types of aromatic and aliphatic SULFIDEs are selectively oxidized to the corresponding SULFOXIDEs in good to excellent yields using 30% H2O2 in the presence of catalytic amounts of N-BROMOSUCCINIMIDE (NBS) in buffered aqueous acetonitrile solution (pH =7.00). The results showed that acid sensitive functional groups such as double bonds, and O,O-acetals remained intact under the described reaction conditions.

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