Journal Paper

Paper Information

Journal: JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC) | Year:1389 | Volume:4 | Issue:13 | Start Page:5 | End Page:11

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Information Journal Paper

Title

SYNTHESIS OF EPOXIDIZED POLYBUTADIENE USING NANOCLAY AS A PHASE TRANSFER CATALYST

Pages

 Start Page 5 | End Page 11

Keywords

IN SITU GENERATED DIMETHYL DIOXIRANE (DMD)Q3

Abstract

EPOXIDIZED POLYBUTADIENE was synthesized using in situ generated dimethyl dioxitanb (DMD) as an oxidant and CLOISITE 30B as a phase transfer catalyst (PIC). The formation of epoxy groups monitored by using FT-IR and NMR spectrospopy methods in various reaction times. addition, a significant selectivity and significant yield increments have been perceived toward Cis carbon-carbon double bonds epoxidation in comparison with Trans epoxidation. The method was fast and eco-friendly and can be considered as a versatile method in polybutadiene epoxidation.

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