Abstract:
In present study, the improvement of adhesion strength of polyurethane and alkyd coatings on the poplar wood (Populus nigra) by nano-silane coating using sol-gel method for outdoor application is investigated. For this purpose, the boards with the dimensions of 15 × 10 × 2 mm were prepared according to EN 927-5. The surfaces of wood specimens were modified with Tetraethoxysilane (T) sol-gel material and then, solvent-borne alkyd (AS) and solvent-borne polyurethane (PS) coatings were applied. The coated samples were placed outdoor on a platform facing south and with a slope of 36 for 8 months according to ISO 877 standard. In order to characterize the quality of the coatings, colorimetric, tensile adhesion (Pull off), scratch adhesion (Cross cut) and ATR-FTIR tests were performed before and after weathering. The ATR-FTIR analysis demonstrated that the wood surface was covered with silicon oxides (SiO2) attached to hydrocarbon chains. As a result of wood surface modification by sol-gel, the color and adhesion strength of polyurethane and alkyd coatings were less affected by weathering. The highest tensile and scratch adhesions were found for the combined sol-gel and polyurethane coatings.
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