Paper Information

Journal:   JOURNAL OF NANOSTRUCTURE IN CHEMISTRY   2018 , Volume 8 , Number 1; Page(s) 33 To 44.
 
Paper: 

ASYMMETRIC ATTACHMENT AND FUNCTIONALIZATION OF PLASMONIC NANOPARTICLES ON CERAMIC INTERFACES

 
 
Author(s):  STADLER DANIEL, SIRIBBAL SHIFAA MOHAMMED, GESSNER ISABEL, OZ SENOL, ILYAS SHAISTA, MATHUR SANJAY*
 
* DEPARTMENT OF CHEMISTRY, INORGANIC CHEMISTRY, UNIVERSITY OF COLOGNE, GREINSTRASSE 6, 50939 COLOGNE, GERMANY
 
Abstract: 

The demands for materials that integrate more than one functional imaging or therapeutic unit are of increasing interest for biomedical applications. Here, we present the step-by-step preparation of asymmetric and optically active particles, namely, Gd2O3@ Ag, Gd2O3@ Au, SiO2–N3@Au, and SiO2–SH@Au. Successful attachment of plasmonic nanoparticles to the surface of metal-oxide spheres without necessity of a potentially toxic inter-adhesive layer was proven by optical methods as well as X-ray photoelectron spectroscopy. The combination of optical and magnetic properties as present in Gd2O3@ Ag and Gd2O3@ Au Janus-type particles leads to dual-imaging probes for optical and magnetic resonance imaging. In addition, functional groups, such as azide groups, were linked to the surface of silica particles previous to Au nanoparticle attachment. Subsequent site-selective click reactions with 5-FAM were successfully performed as demonstrated by UV-Vis measurements. All described systems exhibited excellent long-term stability and can, therefore, be considered as promising candidates for theranostic applications.

 
Keyword(s): THERANOSTICS, JANUS PARTICLES, OPTICAL MATERIALS, SPUTTER DEPOSITION, MAGNETIC
 
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