Paper Information

Journal:   JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)   December 2004 , Volume 1 , Number 2; Page(s) 136 To 140.
 
Paper: 

A NOVEL AND EFFICIENT METHOD FOR THE SYNTHESIS OFA#-AMINONITRILES BY THE REACTION OF AMINALS WITH TRIMETHYLSILYL CYANIDE CATALYZED BY IODINE

 
 
Author(s):  SAEIDI M.R., AZIZI N.
 
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Abstract: 
Iodine, was found to be a practical and novel catalyst for the reaction of aminal and trimethylsilyl cyanide under mild and neutral reaction condition to afford the corresponding ل-aminonitriles in high yields and short reaction times. Trimethylsilyl iodide derived in situ from elemental iodine and trimethylsillyl cyanide catalyzed this conversion.
 
Keyword(s): TRIMETHYLSILYL CYANIDE, CARBONYL COMPOUNDS, IODINE, IMINIUM SALT, AMINAL
 
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