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Paper Information

Journal:   JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)   2014 , Volume 11 , Number 4; Page(s) 985 To 991.
 
Paper: 

SYNTHESIS, CRYSTAL STRUCTURE, AND ELECTROCHEMICAL PROPERTIES OF NI(II) AND CU(II) COMPLEXES WITH TWO UNSYMMETRICAL N2O2 SCHIFF BASE LIGANDS

 
 
Author(s):  MEGHDADI SORAIA, AMIRNASR MEHDI, BAGHERI MARYAM, AHMADI NAJAFABADI FATEMEH, MEREITER KURT, JOB SCHENK KURT, ZIAEE FAHIMEH
 
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Abstract: 

Nickel(II) and copper(II) complexes of two unsymmetrical tetradentate Schiff base ligands [Ni(Me-salabza)] (1), [Cu(Me-salabza)] (2) and [Ni(salabza)] (3), {H2salabza=N,N'-bis[(salicylidene)-2-aminobenzylamine] and H2Me-salabza=N,N'-bis[(methylsalicylidene)-2-aminobenzylamine]}, have been synthesized and characterized by elemental analysis and spectroscopic methods. The crystal structures of 2 and 3 complexes have been determined by single crystal X-ray diffraction. Both copper(II) and nickel(II) ions adopt a distorted square planar geometry in [Cu(Me-salabza)] and [Ni(salabza)] complexes. The cyclic voltammetric studies of these complexes in dichloromethane indicate the electronic effects of the methyl groups on redox potential.

 
Keyword(s): UNSYMMETRICAL N2O2 SCHIFF BASE, NI(II) AND CU(II) COMPLEXES, CRYSTAL STRUCTURE, CYCLIC VOLTAMMETRY
 
 
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APA: Copy

MEGHDADI, S., & AMIRNASR, M., & BAGHERI, M., & AHMADI NAJAFABADI, F., & MEREITER, K., & JOB SCHENK, K., & ZIAEE, F. (2014). SYNTHESIS, CRYSTAL STRUCTURE, AND ELECTROCHEMICAL PROPERTIES OF NI(II) AND CU(II) COMPLEXES WITH TWO UNSYMMETRICAL N2O2 SCHIFF BASE LIGANDS. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 11(4), 985-991. https://www.sid.ir/en/journal/ViewPaper.aspx?id=403355



Vancouver: Copy

MEGHDADI SORAIA, AMIRNASR MEHDI, BAGHERI MARYAM, AHMADI NAJAFABADI FATEMEH, MEREITER KURT, JOB SCHENK KURT, ZIAEE FAHIMEH. SYNTHESIS, CRYSTAL STRUCTURE, AND ELECTROCHEMICAL PROPERTIES OF NI(II) AND CU(II) COMPLEXES WITH TWO UNSYMMETRICAL N2O2 SCHIFF BASE LIGANDS. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS). 2014 [cited 2021May18];11(4):985-991. Available from: https://www.sid.ir/en/journal/ViewPaper.aspx?id=403355



IEEE: Copy

MEGHDADI, S., AMIRNASR, M., BAGHERI, M., AHMADI NAJAFABADI, F., MEREITER, K., JOB SCHENK, K., ZIAEE, F., 2014. SYNTHESIS, CRYSTAL STRUCTURE, AND ELECTROCHEMICAL PROPERTIES OF NI(II) AND CU(II) COMPLEXES WITH TWO UNSYMMETRICAL N2O2 SCHIFF BASE LIGANDS. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), [online] 11(4), pp.985-991. Available: https://www.sid.ir/en/journal/ViewPaper.aspx?id=403355.



 
 
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