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Paper Information

Journal:   IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION A- SCIENCE   2014 , Volume 38 , Number A2; Page(s) 175 To 186.
 
Paper: 

DODECYLBENZENESULFONIC ACID AS AN EFFICIENT, CHEMOSELECTIVE AND REUSABLE CATALYST IN THE ACETYLATION AND FORMYLATION OF ALCOHOLS AND PHENOLS UNDER SOLVENT-FREE CONDITIONS AT ROOM TEMPERATURE

 
 
Author(s):  ESMAEILPOUR M., SARDARIAN A.R.*
 
* CHEMISTRY DEPARTMENT, COLLEGE OF SCIENCES, SHIRAZ UNIVERSITY, SHIRAZ 71454, IRAN
 
Abstract: 

Dodecylbenzenesulfonic acid (DBSA) was used as an efficient, cheap and stable Bronsted catalyst for acetylation of alcohols and phenols and formylation of alcohols under solvent-free conditions. Various primary, secondary and tertiary alcohols were acetylated with acetic anhydride as an acetylating agent under solvent-free conditions in the presence of catalytic amount of DBSA at room temperature. Also, formylation of alcohols was catalyzed by DBSA with ethyl formate in high to excellent yields. This method showed high selectivity in acetylation and formylation of various alcohols and phenols. DBSA was recovered and reused in four successive runs without significant deterioration in catalytic activity.

 
Keyword(s): DODECYLBENZENESULFONIC ACID, ACETYLATION, FORMYLATION, SOLVENT-FREE, REUSABLE CATALYST
 
 
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APA: Copy

ESMAEILPOUR, M., & SARDARIAN, A. (2014). DODECYLBENZENESULFONIC ACID AS AN EFFICIENT, CHEMOSELECTIVE AND REUSABLE CATALYST IN THE ACETYLATION AND FORMYLATION OF ALCOHOLS AND PHENOLS UNDER SOLVENT-FREE CONDITIONS AT ROOM TEMPERATURE. IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION A- SCIENCE, 38(A2), 175-186. https://www.sid.ir/en/journal/ViewPaper.aspx?id=402634



Vancouver: Copy

ESMAEILPOUR M., SARDARIAN A.R.. DODECYLBENZENESULFONIC ACID AS AN EFFICIENT, CHEMOSELECTIVE AND REUSABLE CATALYST IN THE ACETYLATION AND FORMYLATION OF ALCOHOLS AND PHENOLS UNDER SOLVENT-FREE CONDITIONS AT ROOM TEMPERATURE. IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION A- SCIENCE. 2014 [cited 2021May18];38(A2):175-186. Available from: https://www.sid.ir/en/journal/ViewPaper.aspx?id=402634



IEEE: Copy

ESMAEILPOUR, M., SARDARIAN, A., 2014. DODECYLBENZENESULFONIC ACID AS AN EFFICIENT, CHEMOSELECTIVE AND REUSABLE CATALYST IN THE ACETYLATION AND FORMYLATION OF ALCOHOLS AND PHENOLS UNDER SOLVENT-FREE CONDITIONS AT ROOM TEMPERATURE. IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION A- SCIENCE, [online] 38(A2), pp.175-186. Available: https://www.sid.ir/en/journal/ViewPaper.aspx?id=402634.



 
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