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Paper Information

Journal:   IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)   WINTER 2012 , Volume 31 , Number 4 (64); Page(s) 35 To 40.
 
Paper: 

SYNTHESIS AND CHARACTERIZATION OF ACRYLIC COPOLYMERS OF 4-CHLOROMETHYL STYRENE WITH INCORPORATION OF PHTHALIMIDE GROUPS AND AMINATION OF RESULTED POLYMERS

 
 
Author(s):  NOURI MOLALAR MEYSAM, GHASHANGI ZAHED, NASIRTABRIZI MOHAMMAD HOSSEIN*, PARCHEHBAF JADID AIYOUB
 
* DEPARTMENT OF APPLIED CHEMISTRY, ARDABIL BRANCH, ISLAMIC AZAD UNIVERSITY, ARDABIL, I.R. IRAN
 
Abstract: 

4-ChloroMethyl Styrene (CMS) was copolymerized with different monomers such as Methyl Meth Acrylate (MMA), Methyl Acrylate (MA), 2-EthylHexyl Acrylate (EHA) by free radical polymerization method at 70 ±1oC using a,a' -Azobis (Iso Butyro Nitrile) (AIBN) as an initiator.
The copolymer compositions were obtained using related1 HNMR spectra and the polydispersity of the copolymers were determined using Gel Permeation Chromatography (GPC). The amino copolymers were prepared by treating 4-chloromethy styrene copolymers with sodium phthalimide and then with hydrazine monohydrate. The polymers were characterized by1 HNMR and FT-IR spectroscopic techniques. The glass transition temperature (Tg) of all copolymers was determined by Dynamic Mechanical Thermal Analysis (DMTA). Study of DMTA analysis showed that chemical modification of 4-chloromethyl styrene copolymers with phthalimide substituent leads to an increase in the rigidity and glass transition temperature of polymers.

 
Keyword(s): 4-CHLOROMETHYL STYRENE, PHTHALIMIDE, GLASS TRANSITION TEMPERATURE, AMINATED POLYMERS
 
 
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APA: Copy

NOURI MOLALAR, M., & GHASHANGI, Z., & NASIRTABRIZI, M., & PARCHEHBAF JADID, A. (2012). SYNTHESIS AND CHARACTERIZATION OF ACRYLIC COPOLYMERS OF 4-CHLOROMETHYL STYRENE WITH INCORPORATION OF PHTHALIMIDE GROUPS AND AMINATION OF RESULTED POLYMERS. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 31(4 (64)), 35-40. https://www.sid.ir/en/journal/ViewPaper.aspx?id=276846



Vancouver: Copy

NOURI MOLALAR MEYSAM, GHASHANGI ZAHED, NASIRTABRIZI MOHAMMAD HOSSEIN, PARCHEHBAF JADID AIYOUB. SYNTHESIS AND CHARACTERIZATION OF ACRYLIC COPOLYMERS OF 4-CHLOROMETHYL STYRENE WITH INCORPORATION OF PHTHALIMIDE GROUPS AND AMINATION OF RESULTED POLYMERS. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE). 2012 [cited 2021July31];31(4 (64)):35-40. Available from: https://www.sid.ir/en/journal/ViewPaper.aspx?id=276846



IEEE: Copy

NOURI MOLALAR, M., GHASHANGI, Z., NASIRTABRIZI, M., PARCHEHBAF JADID, A., 2012. SYNTHESIS AND CHARACTERIZATION OF ACRYLIC COPOLYMERS OF 4-CHLOROMETHYL STYRENE WITH INCORPORATION OF PHTHALIMIDE GROUPS AND AMINATION OF RESULTED POLYMERS. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), [online] 31(4 (64)), pp.35-40. Available: https://www.sid.ir/en/journal/ViewPaper.aspx?id=276846.



 
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