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Paper Information

Journal:   JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)   MARCH 2008 , Volume 5 , Number 1; Page(s) 135 To 139.
 
Paper: 

IONIC LIQUID-MEDIATED DARZENS CONDENSATION: AN ENVIRONMENTALLY-FRIENDLY PROCEDURE FOR THE ROOM-TEMPERATURE SYNTHESIS OF α,β- EPOXY KETONES

 
 
Author(s):  SHARIFI A.*, ABAEI M.S., MIRZAEI MOJTABA, SALIMI R.
 
* ORGANIC CHEMISTRY DEPARTMENT, CHEMISTRY & CHEMICAL ENGINEERING RESEARCH CENTER OF IRAN, TEHRAN, IRAN
 
Abstract: 
This room-temperature Darzens condensation of a-chloroacetophenone with various aromatic aldehydes mediated by [bmim][BF4] ionic liquid in the presence of sodium tert-butoxide resulted in the sole formation of good to excellent yields of trans-a, b-epoxy ketones in short time periods. In contrast, tert-butyl 2-chloroacetate nderwent Darzens reactions with aldehydes giving mixtures of both cis and trans products with low selectivity. In all reactions, the ionic liquid was recovered and reused in the subsequent reactions without significant loss of activity.
 
Keyword(s): IONIC LIQUIDS, ROOM TEMPERATURE, DARZENS REACTION, α,β-EPOXY KETONES
 
 
References: 
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Citations: 
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+ Click to Cite.
APA: Copy

SHARIFI, A., & ABAEI, M., & MIRZAEI, M., & SALIMI, R. (2008). IONIC LIQUID-MEDIATED DARZENS CONDENSATION: AN ENVIRONMENTALLY-FRIENDLY PROCEDURE FOR THE ROOM-TEMPERATURE SYNTHESIS OF α,β- EPOXY KETONES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 5(1), 135-139. https://www.sid.ir/en/journal/ViewPaper.aspx?id=105776



Vancouver: Copy

SHARIFI A., ABAEI M.S., MIRZAEI MOJTABA, SALIMI R.. IONIC LIQUID-MEDIATED DARZENS CONDENSATION: AN ENVIRONMENTALLY-FRIENDLY PROCEDURE FOR THE ROOM-TEMPERATURE SYNTHESIS OF α,β- EPOXY KETONES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS). 2008 [cited 2021July25];5(1):135-139. Available from: https://www.sid.ir/en/journal/ViewPaper.aspx?id=105776



IEEE: Copy

SHARIFI, A., ABAEI, M., MIRZAEI, M., SALIMI, R., 2008. IONIC LIQUID-MEDIATED DARZENS CONDENSATION: AN ENVIRONMENTALLY-FRIENDLY PROCEDURE FOR THE ROOM-TEMPERATURE SYNTHESIS OF α,β- EPOXY KETONES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), [online] 5(1), pp.135-139. Available: https://www.sid.ir/en/journal/ViewPaper.aspx?id=105776.



 
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