Paper Information

Journal:   JOURNAL OF SCIENCE (UNIVERSITY OF TEHRAN) (JSUT)   SUMMER 2007 , Volume 33 , Number 2 (SECTION: CHEMISTRY); Page(s) 19 To 21.
 
Paper: 

CRYSTAL STRUCTURE OF CIS-RU(DMSO)4CL2 IN DIFFERENT SYNTHETIC METHODS

 
 
Author(s):  TARIGHI S., ABASI A.R.*
 
* SCHOOL OF CHEMISTRY, UNIVERSITY COLLEGE OF SCIENCE, UNIVERSITY OF TEHRAN, TEHRAN, IRAN
 
Abstract: 

The structure of the cis-dichlorotetrakis (dimethyl sulfoxide) ruthenium(II) have been studied by means of single-crystal X-ray diffraction. The data are described in orthorhombic unit cell with space group Pccn (No. 56) at 295 K, a = 28.478 (4) Å, b = 10.900 (6) Å, c = 11.697(13) Å, and V = 3631 (4) Å3, Z = 8. The crystal structure of the title compound comprises a nearly octahedral configuration with a Ru-O bond distance of, 2.151 Å, and the average values of, 2.269 Å and 2.421 Å for Ru-S and Ru-Cl, respectively.

 
Keyword(s): DIVALENT METAL IONS, RUTHENIUM, DIMETHYL SULFOXIDE, COORDINATION CHEMISTRY, CRYSTAL STRUCTURE
 
References: 
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