Paper Information

Journal:   JOURNAL OF SCIENCE (UNIVERSITY OF TEHRAN) (JSUT)   SUMMER 2007 , Volume 33 , Number 2 (SECTION: CHEMISTRY); Page(s) 1 To 6.
 
Paper: 

INFRARED AND RAMAN SPECTROSCOPIC AND FORCE FIELD STUDIES OF Y(H2O)9 (BRO3)3

 
 
Author(s):  ABASI A.R.*, SKRIPKIN M.Y.
 
* SCHOOL OF CHEMISTRY, UNIVERSITY COLLEGE OF SCIENCE, UNIVERSITY OF TEHRAN, TEHRAN, IRAN
 
Abstract: 

Infrared and Raman spectra of the nonaaqua yttrium (III) bromate, Y (H2O)9 (BrO3)3, compound have been recorded. Force field calculations have been performed for YO93+ moiety, with a tricapped trigonal prismatic oxygen atom arrangement in D3h point group symmetry. The larger stretching force constant was found, 90.7 Nm-1, for the Y-O prism in comparison with the corresponding value in the capped Y-O, 56.5 Nm-1.

 
Keyword(s): TRIVALENT METAL IONS, YTTRIUM, HYDRATED COMPOUNDS, COORDINATION, FORCE FILE
 
References: 
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