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Paper Information

Journal:   JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)   JUNE 2011 , Volume 8 , Number 2; Page(s) 570 To 573.
 
Paper: 

PALLADIUM CHLORIDE-CATALYZED REDUCTIVE CLEAVAGE OF BENZYLIC ACETAL, KETAL AND ETHER COMPOUNDS WITH TRIETHYLSILANE

 
 
Author(s):  MIRZA AGHAYAN M.*, BOUKHERROUB R., RAHIMIFARD M., ZADMARD R.
 
* CHEMISTRY AND CHEMICAL ENGINEERING RESEARCH CENTER OF IRAN (CCERCI), TEHRAN, IRAN
 
Abstract: 

Reductive cleavage of benzylic acetal, ketal and ether compounds to the corresponding alkanes using triethylsilane and a catalytic amount of palladium(II) chloride is described. The reductive reaction took place under mild conditions, affording high yields of the corresponding alkane compounds in short reaction times.

 
Keyword(s): REDUCTION, ACETALS, KETALS, ETHERS, PALLADIUM(II) CHLORIDE, TRIETHYLSILANE, ALKANES
 
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